to stop Pipewire and PulseAudio we can use the following commands:
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systemctl --user stop pulseaudio.socket && systemctl --user stop pulseaudio.service
systemctl --user stop pipewire.socket && systemctl --user stop pipewire.service
systemctl --user stop pipewire-pulse.socket && systemctl --user stop pipewire-pulse.service
to disable Pipewire and PulseAudio from starting at login and to ensure that PulseAudio can be stopped without respawning create the following directory using the command...
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mkdir ~/.config/systemd/user/
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systemctl --user mask pulseaudio.socket
systemctl --user mask pipewire.socket
systemctl --user mask pipewire-pulse.socket
systemctl --user mask pulseaudio.service
systemctl --user mask pipewire.service
systemctl --user mask pipewire-pulse.service